The use of tetrahydrofuran derivatives in synthesis of components of sex pheromone of the oriental fruit moth Chemistry

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Published: Dec 15, 2018
Keywords:
sex pheromone, oriental fruit moth, two-synthon strategy, tetrahydrofuran, tetrahydrofurfuryl alcohol, column chromatography.

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N. G. Hobosyan
Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA;  Kh. Abovian Armenian State Pedagogical University
S. А. Hovakimyan
Kh. Abovian Armenian State Pedagogical University
K. V. Balyan
Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA
H. S. Nersisyan
Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA
H. B. Sargsyan
Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA
J. А. Chobanyan
Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

Abstract

Based on available reagents: tetrahydrofurfuryl alcohol and tetrahydrofuran, the technologically easily implemented method of synthesis of the active component of the sex pheromone of Oriental Fruit Moth Grapholitha Molesta with predominant content of (Z)-dodec-8-enyl acetate by two synthon C8+C4 scheme was developed. The condensation stage of C4 and C8 was performed in the presence of dilithium tetrachlorocuprate.

Article Details

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Vol 52 No 3 (2018): Volume 52 No 3
Section
Articles
Author Biographies

N. G. Hobosyan, Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA;  Kh. Abovian Armenian State Pedagogical University

N. G. Hobosyan

Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA;

 Kh. Abovian Armenian State Pedagogical University, Armenia

E-mail: ninahobosyan@mail.ru

S. А. Hovakimyan, Kh. Abovian Armenian State Pedagogical University

S. A. Hovakimyan

Kh. Abovian Armenian State Pedagogical University, Armenia

K. V. Balyan, Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

K. V. Balyan

Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

H. S. Nersisyan, Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

H. S. Nersisyan

Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

H. B. Sargsyan, Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

H. B. Sargsyan

Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

J. А. Chobanyan, Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA

 J. A. Chobanyan

Institute of Organic Chemistry, STC of Organic and Pharmaceutical Chemistry of NAS RA